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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sarkar, Debayan | en_US |
dc.date.accessioned | 2022-11-03T19:56:57Z | - |
dc.date.available | 2022-11-03T19:56:57Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | Sahoo, S. R., Das, B., Sarkar, D., & Reuter, H. (2022). Temperature-controlled chemoselective synthesis of multisubstituted 4-Alkynyl/trans 4-alkenyl coumarins. Journal of Organic Chemistry, doi:10.1021/acs.joc.2c00994 | en_US |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.other | EID(2-s2.0-85139918467) | - |
dc.identifier.uri | https://doi.org/10.1021/acs.joc.2c00994 | - |
dc.identifier.uri | https://dspace.iiti.ac.in/handle/123456789/11024 | - |
dc.description.abstract | A temperature-controlled facile synthesis of multisubstituted 4-alkynyl/trans 4-alkenyl coumarins with a metal salt cascade approach is reported. H2O serves both as a nucleophile and hydrogen source. The presence of metal salt facilitates the reduction of alkyne. The present protocol bypasses the structural shortcomings of the existing Sonogashira and Heck coupling reactions. In addition, the obtained 2,3-disubstituted coumarins are readily transformed into 2,3-disubstituted dihydrocoumarins, which serve as important building blocks in organic transformations. © 2022 American Chemical Society. All rights reserved. | en_US |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.source | Journal of Organic Chemistry | en_US |
dc.title | Temperature-Controlled Chemoselective Synthesis of Multisubstituted 4-Alkynyl/trans 4-Alkenyl Coumarins | en_US |
dc.type | Journal Article | en_US |
Appears in Collections: | Department of Chemistry |
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