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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/11626
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dc.contributor.authorKumar, Ankit Sureshen_US
dc.contributor.authorPriya, Bhanuen_US
dc.contributor.authorSingh, Sanjay Kumaren_US
dc.date.accessioned2023-05-03T15:03:31Z-
dc.date.available2023-05-03T15:03:31Z-
dc.date.issued2023-
dc.identifier.citationKumar, A., Priya, B., & Singh, S. K. (2023). Ruthenium-catalyzed transformation of ethylene glycol for selective hydrogen gas production in water. ACS Sustainable Chemistry and Engineering, 11(10), 3999-4008. doi:10.1021/acssuschemeng.2c04521en_US
dc.identifier.issn2168-0485-
dc.identifier.otherEID(2-s2.0-85149030543)-
dc.identifier.urihttps://doi.org/10.1021/acssuschemeng.2c04521-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/11626-
dc.description.abstractWe developed an efficient process for producing hydrogen gas from aqueous ethylene glycol (EG) at 90-160 °C over a ruthenium catalyst. We achieved a high yield of hydrogen gas (up to 3.0 n(H2)/n(EG)) and formic acid (85% yield) from ethylene glycol in aqueous alkaline medium at 110 °C, where the role of reaction temperature and base concentration was found to be critical in achieving a high yield of H2. The chemical and morphological properties of the synthesized ruthenium catalyst were established using P-XRD, TEM, XPS, and other techniques. Advantageously, the ruthenium catalyst exhibited appreciably high long-term stability for over 70 h, generating ca. 290 L of H2 per gram of Ru with a yield of 1035 L of H2 per L of ethylene glycol. © 2023 American Chemical Societyen_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.sourceACS Sustainable Chemistry and Engineeringen_US
dc.subjectAlkalinityen_US
dc.subjectCatalystsen_US
dc.subjectEthyleneen_US
dc.subjectEthylene glycolen_US
dc.subjectHydrogen productionen_US
dc.subjectPolyolsen_US
dc.subjectRutheniumen_US
dc.subjectAlkaline mediaen_US
dc.subjectEfficient processen_US
dc.subjectGas productionsen_US
dc.subjectHeterogeneous catalysten_US
dc.subjectHigher yielden_US
dc.subjectHydrogen gasen_US
dc.subjectMorphological propertiesen_US
dc.subjectReaction temperatureen_US
dc.subjectRuthenium catalystsen_US
dc.subjectSynthesiseden_US
dc.subjectFormic aciden_US
dc.titleRuthenium-Catalyzed Transformation of Ethylene Glycol for Selective Hydrogen Gas Production in Wateren_US
dc.typeJournal Articleen_US
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