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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/13569
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dc.contributor.authorSarkar, Debayanen_US
dc.date.accessioned2024-04-26T12:43:19Z-
dc.date.available2024-04-26T12:43:19Z-
dc.date.issued2024-
dc.identifier.citationRoy, B., Kuila, P., & Sarkar, D. (2024). Visible-light Catalysed Trifluoromethylthiolation and Related Dearomative Spirocyclizations. Advanced Synthesis and Catalysis. Scopus. https://doi.org/10.1002/adsc.202301208en_US
dc.identifier.issn1615-4150-
dc.identifier.otherEID(2-s2.0-85185467970)-
dc.identifier.urihttps://doi.org/10.1002/adsc.202301208-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/13569-
dc.description.abstractWe conceptualized a radical cyclization approach for the synthesis of SCF3, SAr, SO2Ar and COAr featured spirocyclic [4.5] and [5.5] trienone between biaryls and ArSO2H or ArCOCO2H in presence of RFTA as a photocatalyst whereas the insertion of ArSSAr or AgSCF3 devoid of photocatalyst via an energetically demanding dearomative transformation under visible-light catalysis. The photo-excited charge transfer complex with biaryl tethered ynones provides a way to promote S-centered radical generation followed by its insertion to enable a wide range of biologically important molecules. © 2024 Wiley-VCH GmbH.en_US
dc.language.isoenen_US
dc.publisherJohn Wiley and Sons Incen_US
dc.sourceAdvanced Synthesis and Catalysisen_US
dc.subjectEDA complexen_US
dc.subjectSpirocyclizationen_US
dc.subjectSulfonylationen_US
dc.subjectThiolationen_US
dc.subjectTrifluoromethylthiolationen_US
dc.titleVisible-light Catalysed Trifluoromethylthiolation and Related Dearomative Spirocyclizationsen_US
dc.typeJournal Articleen_US
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