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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Srivastava, Navdeep | en_US |
| dc.contributor.author | Singh, Amrendra Kumar | en_US |
| dc.date.accessioned | 2024-06-28T11:38:30Z | - |
| dc.date.available | 2024-06-28T11:38:30Z | - |
| dc.date.issued | 2024 | - |
| dc.identifier.citation | Srivastava, N., & Singh, A. K. (2024). Protic- or anionic-NHCs with a classical-NHC in a single [Ru(CNC)(PPh3)2Cl]Cl pincer complex: Direct comparison of structure & electronic properties and heterolytic H2 splitting. Dalton Transactions. Scopus. https://doi.org/10.1039/d4dt00623b | en_US |
| dc.identifier.issn | 1477-9226 | - |
| dc.identifier.other | EID(2-s2.0-85190150647) | - |
| dc.identifier.uri | https://doi.org/10.1039/d4dt00623b | - |
| dc.identifier.uri | https://dspace.iiti.ac.in/handle/123456789/13793 | - |
| dc.description.abstract | Herein, we report the first set of pincer complexes 1 and 2 with the general formula [Ru(CNC)(PPh3)2Cl]Cl having a protic- and classical-NHC in the same molecule and nearly identical environments. Deprotonation of the protic-NHC complex 2 with one equivalent of base leads to the formation of anionic-NHC complex 2′. These complexes allow a direct comparison of protic- and anionic-NHCs with the classical-NHC ligand. A comparison of the molecular structure indicated that the metal carbene bond length trend is anionic-NHC > | en_US |
| dc.description.abstract | protic-NHC > | en_US |
| dc.description.abstract | classical-NHC. The electrochemical investigation revealed the electron donation tendency is classical-NHC > | en_US |
| dc.description.abstract | protic-NHC and anionic-NHC > | en_US |
| dc.description.abstract | protic-NHC. Cooperation between the metal and the ligand is indicated by the reaction of 2′ with H2 gas at 1 atm pressure and 110 °C to give the Ru-hydride complex 3. © 2024 The Royal Society of Chemistry. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Royal Society of Chemistry | en_US |
| dc.source | Dalton Transactions | en_US |
| dc.title | Protic- or anionic-NHCs with a classical-NHC in a single [Ru(CNC)(PPh3)2Cl]Cl pincer complex: direct comparison of structure & | en_US |
| dc.title | electronic properties and heterolytic H2 splitting | en_US |
| dc.type | Journal Article | en_US |
| Appears in Collections: | Department of Chemistry | |
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