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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/14198
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dc.contributor.authorSarkar, Debayanen_US
dc.date.accessioned2024-08-14T10:23:42Z-
dc.date.available2024-08-14T10:23:42Z-
dc.date.issued2024-
dc.identifier.citationKuila, P., Roy, B., & Sarkar, D. (2024). High Yield Synthesis of Spirocyclic Dienones from Phenols Employing Tribromide Catalysed Dearomatization. European Journal of Organic Chemistry. https://doi.org/10.1002/ejoc.202400267en_US
dc.identifier.issn1434-193X-
dc.identifier.otherEID(2-s2.0-85197447599)-
dc.identifier.urihttps://doi.org/10.1002/ejoc.202400267-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/14198-
dc.description.abstractA catalytic strategy towards the tribromide-catalyzed dearomative spirocyclization reaction is described employing tetrabutylammonium bromide (TBAB) and oxone as an oxidising agent. This methodology leads to the exclusive formation of spirofurano dienones without rearomatization or halogenation. Our group has been on trails of tribromide-catalyzed dearomative transformation during the last decade, and now this exhibits the first report which delivers high functional group tolerance and broad substrate scope with excellent yield (up to 99 %) and good diastereoselectivity (dr up to 14 : 1). The oxidation of naphthols as well as phenols is achieved under this mild conditions. © 2024 Wiley-VCH GmbH.en_US
dc.language.isoenen_US
dc.publisherJohn Wiley and Sons Incen_US
dc.sourceEuropean Journal of Organic Chemistryen_US
dc.subjectarenolsen_US
dc.subjectdearomatizationen_US
dc.subjectgreen oxidanten_US
dc.subjectSpiro-furanen_US
dc.subjecttribromide-catalysisen_US
dc.titleHigh Yield Synthesis of Spirocyclic Dienones from Phenols Employing Tribromide Catalysed Dearomatizationen_US
dc.typeJournal Articleen_US
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