Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/16383
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dc.contributor.authorBunkar, Rajendraen_US
dc.contributor.authorMulani, Sameena R.en_US
dc.contributor.authorBimli, Santoshen_US
dc.contributor.authorDevan, Rupesh S.en_US
dc.date.accessioned2025-07-09T13:47:59Z-
dc.date.available2025-07-09T13:47:59Z-
dc.date.issued2025-
dc.identifier.citationBunkar, R. P., Mulani, S. R., Bimli, S., Dohare, A., Varshney, M., Roy, T., Jangir, R., Thakare, V. B., & Devan, R. S. (2025). Metal-organic framework-5 and graphene oxide (MOF-5@GO) composite for effective detoxification of highly hazardous sulfur mustard. Surfaces and Interfaces, 72. https://doi.org/10.1016/j.surfin.2025.107030en_US
dc.identifier.issn2468-0230-
dc.identifier.otherEID(2-s2.0-105009006568)-
dc.identifier.urihttps://dx.doi.org/10.1016/j.surfin.2025.107030-
dc.identifier.urihttps://dspace.iiti.ac.in:8080/jspui/handle/123456789/16383-
dc.description.abstractSulfur mustard (SM) poses serious threats of intentional use against civilians, so it requires utmost and immediate attention for detoxification. Therefore, Metal-Organic Framework-5 (MOF-5), Graphene Oxide (GO), and MOF-5@GO composite materials are explored for effective detoxification of SM. The crystalline MOF-5@GO, having cubic morphology with a porous structure and abundant functional sites due to surface modification, is found to be responsible for the efficient adsorption of SM. Thermally stable MOF-5@GO consisting of Zn, C, and O in their stoichiometric form exhibits a high active surface area of ∼407.38 m2/g, which provides more accessible sites for adsorption of SM and, thereafter, detoxification. The synergistic interactions between MOF-5 and GO in the MOF-5@GO composite delivered 92 % adsorption for the SM, which is ∼2.5 and ∼1.6 times higher than pristine GO and MOF-5, respectively. The adsorptive removal of SM exhibits pseudo-first-order kinetics with rate constant (k), half-life (t1/2), and maximum adsorption capacity (qmax) of 24.66 × 10–2/h, 2.81 h, and 18.01 mg/g, respectively. The GC–MS analysis reveals better degradation of sulfur mustard into relatively non-toxic thiodiglycol, etc., products for the MOF-5@GO composite. Therefore, MOF-5@GO is a very efficient and eco-friendly contender for outstanding performance in detoxifying highly hazardous SM. © 2025en_US
dc.language.isoenen_US
dc.publisherElsevier B.V.en_US
dc.sourceSurfaces and Interfacesen_US
dc.subjectDetoxificationen_US
dc.subjectMOF-5en_US
dc.subjectMOF-5@GO compositeen_US
dc.subjectSolvothermalen_US
dc.subjectSulfur mustarden_US
dc.titleMetal-organic framework-5 and graphene oxide (MOF-5@GO) composite for effective detoxification of highly hazardous sulfur mustarden_US
dc.typeJournal Articleen_US
Appears in Collections:Department of Metallurgical Engineering and Materials Sciences

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