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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/16433
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dc.contributor.authorSingh, Ashuen_US
dc.contributor.authorJaiswal, Vishalen_US
dc.contributor.authorSingh, Amrendra Kumaren_US
dc.date.accessioned2025-07-09T13:48:02Z-
dc.date.available2025-07-09T13:48:02Z-
dc.date.issued2025-
dc.identifier.citationSingh, A., Jaiswal, V., Misra, S., & Singh, A. K. (2025). Metal–Ligand Cooperativity via Π–Π Interactions Supporting Outer-Sphere Hydride Transfer. Chemistry - A European Journal. https://doi.org/10.1002/chem.202501301en_US
dc.identifier.issn0947-6539-
dc.identifier.otherEID(2-s2.0-105008761703)-
dc.identifier.urihttps://dx.doi.org/10.1002/chem.202501301-
dc.identifier.urihttps://dspace.iiti.ac.in:8080/jspui/handle/123456789/16433-
dc.description.abstractA set of phosphine-free Ru(II)-CNC pincer complexes with benzimidazolylidene-based CNC-ligands has been synthesized and characterized, which show excellent catalytic activity toward α-alkylation of ketones using primary alcohols. DFT investigations revealed that these seemingly nonbifunctional complexes can operate via inner- and outer-sphere mechanisms for the alcohol dehydrogenation stepen_US
dc.description.abstracthowever, the outer-sphere path is favored for the subsequent steps. The outer-sphere path is found to be supported by π–π interaction between the extended aromatic ring system of the benzimidazolylidene-based CNC-ligand and aromatic rings of the substrates in a new, unprecedented case of metal–ligand cooperativity. © 2025 Wiley-VCH GmbH.en_US
dc.language.isoenen_US
dc.publisherJohn Wiley and Sons Incen_US
dc.sourceChemistry - A European Journalen_US
dc.subjectinner-sphere mechanismen_US
dc.subjectmetal–ligand cooperativityen_US
dc.subjectouter-sphere mechanismen_US
dc.subjectα-alkylationen_US
dc.subjectπ–π interactionsen_US
dc.titleMetal–Ligand Cooperativity via Π–Π Interactions Supporting Outer-Sphere Hydride Transferen_US
dc.typeJournal Articleen_US
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