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DC Field | Value | Language |
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dc.contributor.author | Singh, Ashu | en_US |
dc.contributor.author | Jaiswal, Vishal | en_US |
dc.contributor.author | Singh, Amrendra Kumar | en_US |
dc.date.accessioned | 2025-07-09T13:48:02Z | - |
dc.date.available | 2025-07-09T13:48:02Z | - |
dc.date.issued | 2025 | - |
dc.identifier.citation | Singh, A., Jaiswal, V., Misra, S., & Singh, A. K. (2025). Metal–Ligand Cooperativity via Π–Π Interactions Supporting Outer-Sphere Hydride Transfer. Chemistry - A European Journal. https://doi.org/10.1002/chem.202501301 | en_US |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.other | EID(2-s2.0-105008761703) | - |
dc.identifier.uri | https://dx.doi.org/10.1002/chem.202501301 | - |
dc.identifier.uri | https://dspace.iiti.ac.in:8080/jspui/handle/123456789/16433 | - |
dc.description.abstract | A set of phosphine-free Ru(II)-CNC pincer complexes with benzimidazolylidene-based CNC-ligands has been synthesized and characterized, which show excellent catalytic activity toward α-alkylation of ketones using primary alcohols. DFT investigations revealed that these seemingly nonbifunctional complexes can operate via inner- and outer-sphere mechanisms for the alcohol dehydrogenation step | en_US |
dc.description.abstract | however, the outer-sphere path is favored for the subsequent steps. The outer-sphere path is found to be supported by π–π interaction between the extended aromatic ring system of the benzimidazolylidene-based CNC-ligand and aromatic rings of the substrates in a new, unprecedented case of metal–ligand cooperativity. © 2025 Wiley-VCH GmbH. | en_US |
dc.language.iso | en | en_US |
dc.publisher | John Wiley and Sons Inc | en_US |
dc.source | Chemistry - A European Journal | en_US |
dc.subject | inner-sphere mechanism | en_US |
dc.subject | metal–ligand cooperativity | en_US |
dc.subject | outer-sphere mechanism | en_US |
dc.subject | α-alkylation | en_US |
dc.subject | π–π interactions | en_US |
dc.title | Metal–Ligand Cooperativity via Π–Π Interactions Supporting Outer-Sphere Hydride Transfer | en_US |
dc.type | Journal Article | en_US |
Appears in Collections: | Department of Chemistry |
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