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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/8472
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dc.contributor.authorSagdeo, Pankaj R.en_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:17:05Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:17:05Z-
dc.date.issued2015-
dc.identifier.citationSingh, S. D., Nandanwar, V., Srivastava, H., Yadav, A. K., Bhakar, A., Sagdeo, P. R., . . . Ganguli, T. (2015). Determination of the optical gap bowing parameter for ternary Ni1-xZnxO cubic rocksalt solid solutions. Dalton Transactions, 44(33), 14793-14798. doi:10.1039/c5dt02283een_US
dc.identifier.issn1477-9226-
dc.identifier.otherEID(2-s2.0-84939209136)-
dc.identifier.urihttps://doi.org/10.1039/c5dt02283e-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/8472-
dc.description.abstractThe lattice parameter variation for phase pure cubic rocksalt (RS) Ni1-xZnxO ternary solid solutions is observed to be perfectly governed by Vegard's law. X-ray absorption near edge spectroscopy confirms the RS symmetry of Zn atoms in the cubic lattice of Ni1-xZnxO. The optical gap bowing parameter for RS Ni1-xZnxO ternary solid solutions is determined, using diffuse reflectivity, to be -0.93 ± 0.05 eV. The negative value of the bowing indicates a repulsive interaction between the ligand O-2p and the metal Ni-3d orbitals. The determined value of the bowing parameter can be useful in designing UV photodetectors based on Ni1-xZnxO solid solutions. © 2015 Royal Society of Chemistry.en_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.sourceDalton Transactionsen_US
dc.subjectX ray absorptionen_US
dc.subjectBowing parametersen_US
dc.subjectCubic latticeen_US
dc.subjectDiffuse reflectivityen_US
dc.subjectNegative valuesen_US
dc.subjectRepulsive interactionsen_US
dc.subjectTernary solid solutionsen_US
dc.subjectUV photodetectorsen_US
dc.subjectX-ray absorption near edge spectroscopyen_US
dc.subjectSolid solutionsen_US
dc.titleDetermination of the optical gap bowing parameter for ternary Ni1-xZnxO cubic rocksalt solid solutionsen_US
dc.typeJournal Articleen_US
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