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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/8712
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dc.contributor.authorRadhe Shyamen_US
dc.contributor.authorRaghuvanshi, Abhinaven_US
dc.contributor.authorMathur, Pradeepen_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:29:34Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:29:34Z-
dc.date.issued2021-
dc.identifier.citationJi, R. S., Raghuvanshi, A., Jha, B., & Mathur, P. (2021). Reactions of [Ru6(μ6–-C)(C6H5CH3)(CO)14]: Synthesis of some new ru-pt carbonyl clusters and diphosphine substitution. Journal of Organometallic Chemistry, 938 doi:10.1016/j.jorganchem.2021.121755en_US
dc.identifier.issn0022-328X-
dc.identifier.otherEID(2-s2.0-85101956561)-
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2021.121755-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/8712-
dc.description.abstractThree new RuPt clusters [Ru6Pt(μ6–-C)(C6H5CH3)(CO)13(COD)] (2), [Ru6Pt(μ6–-C)(C6H5CH3)(CO)14(PPh3)] (3) and [Ru6Pt2(μ6–-C)(C6H5CH3)(CO)13(PPh3)3] (4) were obtained from the reaction of [Ru6(μ6–-C)(C6H5CH3)(CO)14] (1) with two different Pt precursors. Both 2 and 3 consists of a Ru6Pt cluster with face capped octahedron metal core, whereas, 4 has a unique Ru6Pt2 cluster core structure with doubly capped octahedron. Further, CO substitution behavior of 1 was studied with diphosphine ligands, which results in the formation of mono and bi substituted products, which also show the removal of the toluene cap by the dppe ligand. All the compounds were characterized structurally by X-ray diffraction analysis. © 2021 Elsevier B.V.en_US
dc.language.isoenen_US
dc.publisherElsevier B.V.en_US
dc.sourceJournal of Organometallic Chemistryen_US
dc.subjectBinary alloysen_US
dc.subjectLigandsen_US
dc.subjectPhosphorus compoundsen_US
dc.subjectPlatinum alloysen_US
dc.subjectPlatinum compoundsen_US
dc.subjectRutheniumen_US
dc.subjectRuthenium alloysen_US
dc.subjectRuthenium compoundsen_US
dc.subjectX ray powder diffractionen_US
dc.subjectAreneen_US
dc.subjectCarbonyl clustersen_US
dc.subjectClusteren_US
dc.subjectCluster coresen_US
dc.subjectCore structureen_US
dc.subjectDiphosphinesen_US
dc.subjectMetal coreen_US
dc.subjectPhosphineen_US
dc.subjectPt clustersen_US
dc.subjectPt precursorsen_US
dc.subjectPlatinumen_US
dc.titleReactions of [Ru6(μ6–-C)(C6H5CH3)(CO)14]: Synthesis of some new Ru-Pt carbonyl clusters and diphosphine substitutionen_US
dc.typeJournal Articleen_US
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