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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Radhe Shyam | en_US |
dc.contributor.author | Singh, Amrendra Kumar | en_US |
dc.contributor.author | Pathak, Biswarup | en_US |
dc.contributor.author | Mobin, Shaikh M. | en_US |
dc.contributor.author | Mathur, Pradeep | en_US |
dc.date.accessioned | 2022-03-17T01:00:00Z | - |
dc.date.accessioned | 2022-03-21T11:29:55Z | - |
dc.date.available | 2022-03-17T01:00:00Z | - |
dc.date.available | 2022-03-21T11:29:55Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Ji, R. S., Tauqeer, M., Singh, A. K., Pathak, B., Shaikh, M. M., & Mathur, P. (2020). Unusual demetalation of iron from [2]ferrocenophane skeleton of di-nuclear ferracycle carbonyl complex. Applied Organometallic Chemistry, 34(4) doi:10.1002/aoc.5431 | en_US |
dc.identifier.issn | 0268-2605 | - |
dc.identifier.other | EID(2-s2.0-85078625414) | - |
dc.identifier.uri | https://doi.org/10.1002/aoc.5431 | - |
dc.identifier.uri | https://dspace.iiti.ac.in/handle/123456789/8818 | - |
dc.description.abstract | Photolysis of a hexane solution containing 1,1′- bis (trimethylsilylethynyl)ferrocene (1) and Fe (CO)5, under argon at 0 °C led to the formation of dinuclear complexes [Fe (CO)2{η2:η2 – C (SiMe3) = C(C5H4)FeC(C5H4) = C (SiMe3)Fe (CO)3}–μ–CO] (2) and [Fe (CO)2{η2:η2–C (SiMe3) = C(C5H5)–C(C5H5) = C (SiMe3)Fe (CO)3}–μ–CO] (3). DFT calculations support the experimentally observed demetalation of ferrocene unit of 2 to 3 in presence of water. These compounds were comprehensively characterized by IR and 1H and 13C NMR spectroscopy and crystallographically (1 and 3). © 2020 John Wiley & Sons, Ltd. | en_US |
dc.language.iso | en | en_US |
dc.publisher | John Wiley and Sons Ltd | en_US |
dc.source | Applied Organometallic Chemistry | en_US |
dc.subject | Nuclear magnetic resonance spectroscopy | en_US |
dc.subject | Organometallics | en_US |
dc.subject | Photolysis | en_US |
dc.subject | 13C NMR spectroscopy | en_US |
dc.subject | Carbonyl complexes | en_US |
dc.subject | Demetalation | en_US |
dc.subject | Dinuclear complex | en_US |
dc.subject | Ferrocenophanes | en_US |
dc.subject | Hexane solutions | en_US |
dc.subject | Iron carbonyl | en_US |
dc.subject | Presence of water | en_US |
dc.subject | Iron compounds | en_US |
dc.title | Unusual demetalation of iron from [2]ferrocenophane skeleton of di-nuclear ferracycle carbonyl complex | en_US |
dc.type | Journal Article | en_US |
Appears in Collections: | Department of Chemistry |
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