Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/8818
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dc.contributor.authorRadhe Shyamen_US
dc.contributor.authorSingh, Amrendra Kumaren_US
dc.contributor.authorPathak, Biswarupen_US
dc.contributor.authorMobin, Shaikh M.en_US
dc.contributor.authorMathur, Pradeepen_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:29:55Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:29:55Z-
dc.date.issued2020-
dc.identifier.citationJi, R. S., Tauqeer, M., Singh, A. K., Pathak, B., Shaikh, M. M., & Mathur, P. (2020). Unusual demetalation of iron from [2]ferrocenophane skeleton of di-nuclear ferracycle carbonyl complex. Applied Organometallic Chemistry, 34(4) doi:10.1002/aoc.5431en_US
dc.identifier.issn0268-2605-
dc.identifier.otherEID(2-s2.0-85078625414)-
dc.identifier.urihttps://doi.org/10.1002/aoc.5431-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/8818-
dc.description.abstractPhotolysis of a hexane solution containing 1,1′- bis (trimethylsilylethynyl)ferrocene (1) and Fe (CO)5, under argon at 0 °C led to the formation of dinuclear complexes [Fe (CO)2{η2:η2 – C (SiMe3) = C(C5H4)FeC(C5H4) = C (SiMe3)Fe (CO)3}–μ–CO] (2) and [Fe (CO)2{η2:η2–C (SiMe3) = C(C5H5)–C(C5H5) = C (SiMe3)Fe (CO)3}–μ–CO] (3). DFT calculations support the experimentally observed demetalation of ferrocene unit of 2 to 3 in presence of water. These compounds were comprehensively characterized by IR and 1H and 13C NMR spectroscopy and crystallographically (1 and 3). © 2020 John Wiley & Sons, Ltd.en_US
dc.language.isoenen_US
dc.publisherJohn Wiley and Sons Ltden_US
dc.sourceApplied Organometallic Chemistryen_US
dc.subjectNuclear magnetic resonance spectroscopyen_US
dc.subjectOrganometallicsen_US
dc.subjectPhotolysisen_US
dc.subject13C NMR spectroscopyen_US
dc.subjectCarbonyl complexesen_US
dc.subjectDemetalationen_US
dc.subjectDinuclear complexen_US
dc.subjectFerrocenophanesen_US
dc.subjectHexane solutionsen_US
dc.subjectIron carbonylen_US
dc.subjectPresence of wateren_US
dc.subjectIron compoundsen_US
dc.titleUnusual demetalation of iron from [2]ferrocenophane skeleton of di-nuclear ferracycle carbonyl complexen_US
dc.typeJournal Articleen_US
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