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Title: | Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes |
Authors: | Roy, Dipak Kumar |
Keywords: | Boron compounds;Computation theory;Density functional theory;Electronic properties;Hydrides;Mass spectrometry;Nuclear magnetic resonance spectroscopy;Ruthenium;Substitution reactions;X ray powder diffraction;boranes;Borohydrides;Borylenes;sigma boranes;Steric effect;Synthesis (chemical) |
Issue Date: | 2019 |
Publisher: | Wiley-VCH Verlag |
Citation: | Lenczyk, C., Roy, D. K., Nitsch, J., Radacki, K., Rauch, F., Dewhurst, R. D., . . . Braunschweig, H. (2019). Steric effects dictate the formation of terminal arylborylene complexes of ruthenium from dihydroboranes. Chemistry - A European Journal, 25(59), 13566-13571. doi:10.1002/chem.201902890 |
Abstract: | The steric and electronic properties of aryl substituents in monoaryl borohydrides (Li[ArBH3]) and dihydroboranes were systematically varied and their reactions with [Ru(PCy3)2HCl(H2)] (Cy: cyclohexyl) were studied, resulting in bis(σ)-borane or terminal borylene complexes of ruthenium. These variations allowed for the investigation of the factors involved in the activation of dihydroboranes in the synthesis of terminal borylene complexes. The complexes were studied by multinuclear NMR spectroscopy, mass spectrometry, X-ray diffraction analysis, and density functional theory (DFT) calculations. The experimental and computational results suggest that the ortho-substitution of the aryl groups is necessary for the formation of terminal borylene complexes. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
URI: | https://doi.org/10.1002/chem.201902890 https://dspace.iiti.ac.in/handle/123456789/8864 |
ISSN: | 0947-6539 |
Type of Material: | Journal Article |
Appears in Collections: | Department of Chemistry |
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