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https://dspace.iiti.ac.in/handle/123456789/8981
| Title: | Redox-Active Dynamic Self-Supporting Thixotropic 3D-Printable G-Quadruplex Hydrogels |
| Authors: | Biswas, Ankan Maiti, Sayan Das, Apurba Kumar |
| Keywords: | DNA sequences;Esters;Hydrogels;Iron compounds;Organometallics;Redox reactions;Boronate esters;Ferrocene moiety;Ferrocenium;G-quadruplexes;Guanosines;Printable materials;Redox-active;thixotropic;3D printers |
| Issue Date: | 2018 |
| Publisher: | John Wiley and Sons Ltd |
| Citation: | Biswas, A., Maiti, S., Kalaskar, D. M., & Das, A. K. (2018). Redox-active dynamic self-supporting thixotropic 3D-printable G-quadruplex hydrogels. Chemistry - an Asian Journal, 13(24), 3928-3934. doi:10.1002/asia.201801409 |
| Abstract: | Redox-active G-quadruplex hydrogels were prepared by dynamic boronate ester formation between ferroceneboronic acid and guanosine. Dynamic boronate esters imparted thixotropic and 3D-printability to the hydrogel. Initially, the ferrocene moiety was oxidised to produce a weaker ferrocenium-based green hydrogel. However, the less stable ferrocenium converted into more stable ferrocene to produce a hydrophobic, water-stable and robust hydrogel. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
| URI: | https://doi.org/10.1002/asia.201801409 https://dspace.iiti.ac.in/handle/123456789/8981 |
| ISSN: | 1861-4728 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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