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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/9097
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dc.contributor.authorBiswas, Soumenen_US
dc.contributor.authorMajee, Debashisen_US
dc.contributor.authorGuin, Soumitraen_US
dc.contributor.authorSamanta, Sampaken_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:31:02Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:31:02Z-
dc.date.issued2017-
dc.identifier.citationBiswas, S., Majee, D., Guin, S., & Samanta, S. (2017). Metal- and solvent-free approach to diversely substituted picolinates via domino reaction of cyclic sulfamidate imines with β,γ-unsaturated α-ketocarbonyls. Journal of Organic Chemistry, 82(20), 10928-10938. doi:10.1021/acs.joc.7b01792en_US
dc.identifier.issn0022-3263-
dc.identifier.otherEID(2-s2.0-85031897450)-
dc.identifier.urihttps://doi.org/10.1021/acs.joc.7b01792-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/9097-
dc.description.abstractAn efficient, solvent-free, and eco-friendly domino reaction of 5/6-membered cyclic sulfamidate imines with a variety of β, γ-unsaturated α-ketocarbonyls in neat conditions under MW irradiation promoted by DABCO as a solid organobase has been developed for the rapid construction of a novel class of densely functionalized picolinates. This interesting metal-solvent-free tactic allows a wide range of useful functionalities on the aryl rings and delivers good to excellent yields of the aforesaid aza-heterocycles within short time spans (20-40 min). A biologically promising imidazo[1,2-a]pyridine was successfully synthesized through our unique procedure. © 2017 American Chemical Society.en_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.sourceJournal of Organic Chemistryen_US
dc.subjectReaction kineticsen_US
dc.subjectSynthesis (chemical)en_US
dc.subjectAza-heterocyclesen_US
dc.subjectDomino reactionsen_US
dc.subjectEco-friendlyen_US
dc.subjectFunctionalizeden_US
dc.subjectImidazo[1 ,2-a]pyridineen_US
dc.subjectMetal solventen_US
dc.subjectRapid constructionen_US
dc.subjectSolvent freeen_US
dc.subjectSolventsen_US
dc.subject1,4 diazabicyclo[2.2.2]octaneen_US
dc.subjectcarbonyl derivativeen_US
dc.subjectheterocyclic compounden_US
dc.subjectimidazo[ 1,2 a]pyridineen_US
dc.subjectimineen_US
dc.subjectmetalen_US
dc.subjectpicolinic acid derivativeen_US
dc.subjectpyridine derivativeen_US
dc.subjectsolventen_US
dc.subjectsulfamide derivativeen_US
dc.subjectunclassified drugen_US
dc.subjectannulation reactionen_US
dc.subjectArticleen_US
dc.subjectarylationen_US
dc.subjectchemical structureen_US
dc.subjectcyclizationen_US
dc.subjectdrug synthesisen_US
dc.subjectmicrowave irradiationen_US
dc.subjectorganic chemistryen_US
dc.subjectsubstitution reactionen_US
dc.titleMetal- and Solvent-Free Approach to Diversely Substituted Picolinates via Domino Reaction of Cyclic Sulfamidate Imines with β,γ-Unsaturated α-Ketocarbonylsen_US
dc.typeJournal Articleen_US
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