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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/9166
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dc.contributor.authorMathur, Pradeepen_US
dc.contributor.authorRadhe Shyamen_US
dc.contributor.authorRaghuvanshi, Abhinaven_US
dc.contributor.authorMobin, Shaikh M.en_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:31:23Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:31:23Z-
dc.date.issued2017-
dc.identifier.citationMathur, P., Ji, R. S., Raghuvanshi, A., Tauqeer, M., & Mobin, S. M. (2017). Cleavage of phosphorus-sulfur bond and formation of (μ4-S)Fe4core from photochemical reactions of fe(CO)5with [(RO)2PS2]2; (R = me, et,iPr). Journal of Organometallic Chemistry, 835, 31-38. doi:10.1016/j.jorganchem.2017.02.036en_US
dc.identifier.issn0022-328X-
dc.identifier.otherEID(2-s2.0-85014288102)-
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2017.02.036-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/9166-
dc.description.abstractWhen hexane or alcohol solutions containing iron pentacarbonyl and bis(dialkoxythiophosphoryl) disulfide (R = Me (1), Et (2), or Pri(3)), were irradiated with 366 nm light, under argon atmosphere at 0 °C, clusters [(μ-RS)Fe2(CO)6](μ4-S)[(μ-(OR)2P)Fe2(CO)6] (4: R = Me, 5: R = Et) and [Fe2(CO)6S{P(OiPr)2}]2(6) were obtained in hexane and [Fe4(CO)8(μ-CO)2(μ4-S)2P(OR)3] (7: R = Me, 8: R = Et) in MeOH and EtOH respectively. These reactions involve P–S bond cleavage of ligands and desulfurization process and Fe-S and Fe-P bond formation. Computational and experimental bond parameters have been studied on the new compounds. © 2017en_US
dc.language.isoenen_US
dc.publisherElsevier B.V.en_US
dc.sourceJournal of Organometallic Chemistryen_US
dc.subjectCrystal structureen_US
dc.subjectDesulfurizationen_US
dc.subjectHexaneen_US
dc.subjectPhosphorusen_US
dc.subjectPhotochemical reactionsen_US
dc.subjectSulfuren_US
dc.subjectSulfur compoundsen_US
dc.subjectAlcohol solutionsen_US
dc.subjectArgon atmospheresen_US
dc.subjectBond cleavagesen_US
dc.subjectBond formationen_US
dc.subjectDe-sulfurization processen_US
dc.subjectIron pentacarbonylsen_US
dc.subjectIron compoundsen_US
dc.titleCleavage of phosphorus-sulfur bond and formation of (μ4-S)Fe4core from photochemical reactions of Fe(CO)5with [(RO)2PS2]2; (R = Me, Et,iPr)en_US
dc.typeJournal Articleen_US
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