Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/9183
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dc.contributor.authorBhattacharya, Tamalikaen_US
dc.contributor.authorMajumdar, Bijuen_US
dc.contributor.authorSarma, Tridib Kumaren_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:31:29Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:31:29Z-
dc.date.issued2016-
dc.identifier.citationBhattacharya, T., Majumdar, B., & Sarma, T. K. (2016). Compositional effect in AuPd bimetallic nanoparticles towards product selectivity during aerobic oxidation of α-hydroxy esters and phosphonates. ChemistrySelect, 1(16), 5265-5269. doi:10.1002/slct.201601021en_US
dc.identifier.issn2365-6549-
dc.identifier.otherEID(2-s2.0-85041962233)-
dc.identifier.urihttps://doi.org/10.1002/slct.201601021-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/9183-
dc.description.abstractAerobic oxidation of α-hydroxy esters and phosphonates for direct formation of α-keto esters and α-keto phosphonates was explored using Au nanoparticle based catalytic systems. Alloying Au with Pd resulted in high activity and selectivity for the aerobic oxidation reaction under base and solvent free conditions. The formation of desired α-keto esters and α-keto phosphonates as sole products were highly dependent on the composition of the alloy nanocatalyst. Addition of a secondary oxidizer such as tert-butylhydroperoxide (TBHP) significantly enhanced the yield of the products at shorter reaction time under mild reaction conditions. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.sourceChemistrySelecten_US
dc.titleCompositional Effect in AuPd Bimetallic Nanoparticles Towards Product Selectivity during Aerobic Oxidation of α-Hydroxy Esters and Phosphonatesen_US
dc.typeJournal Articleen_US
Appears in Collections:Department of Chemistry

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