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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/9299
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dc.contributor.authorMisra, Rajneeshen_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:32:10Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:32:10Z-
dc.date.issued2015-
dc.identifier.citationMisra, R., Gautam, P., & Maragani, R. (2015). Ferrocenyl thiazoles: Synthesis and properties. Tetrahedron Letters, 56(13), 1664-1666. doi:10.1016/j.tetlet.2015.02.031en_US
dc.identifier.issn0040-4039-
dc.identifier.otherEID(2-s2.0-84924243507)-
dc.identifier.urihttps://doi.org/10.1016/j.tetlet.2015.02.031-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/9299-
dc.description.abstractA set of ferrocenyl-substituted thiazoles 2 and 3 were designed and synthesized by Pd-catalyzed Sonogashira cross-coupling reaction. Their [2+2] cycloaddition-reteroelectrocyclization reaction with tetracyanoethene resulted in strong intramolecular charge transfer (ICT) chromophores 4 and 5. The electronic absorption spectra of 4 and 5 exhibit strong ICT bands in the near infrared (NIR) region. The electrochemical studies of ferrocenyl thiazoles 4 and 5 exhibit multistep redox waves. The computational studies show good agreement with the experimental results. The incorporation of 1,1,4,4-tetracyanobuta-1,3-diene (TCBD) unit results is improved thermal stability of ferrocenyl thiazoles. © 2015 Elsevier Ltd. All rights reserved.en_US
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.sourceTetrahedron Lettersen_US
dc.subjectferrocene derivativeen_US
dc.subjectthiazole derivativeen_US
dc.subjectArticleen_US
dc.subjectchromatophoreen_US
dc.subjectconjugationen_US
dc.subjectcyclizationen_US
dc.subjectcycloadditionen_US
dc.subjectdensity functional theoryen_US
dc.subjectenergy absorptionen_US
dc.subjectoxidationen_US
dc.subjectoxidation reduction potentialen_US
dc.subjectreductionen_US
dc.subjectSonogashira reactionen_US
dc.subjectsynthesisen_US
dc.subjectthermogravimetryen_US
dc.subjectthermostabilityen_US
dc.titleFerrocenyl thiazoles: Synthesis and propertiesen_US
dc.typeJournal Articleen_US
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