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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Misra, Rajneesh | en_US |
| dc.date.accessioned | 2022-03-17T01:00:00Z | - |
| dc.date.accessioned | 2022-03-21T11:32:14Z | - |
| dc.date.available | 2022-03-17T01:00:00Z | - |
| dc.date.available | 2022-03-21T11:32:14Z | - |
| dc.date.issued | 2015 | - |
| dc.identifier.citation | Misra, R., & Gautam, P. (2015). Meso-tetrakis(ferrocenylethynylphenyl) porphyrins: Synthesis and properties. Journal of Organometallic Chemistry, 776, 83-88. doi:10.1016/j.jorganchem.2014.11.006 | en_US |
| dc.identifier.issn | 0022-328X | - |
| dc.identifier.other | EID(2-s2.0-84949116838) | - |
| dc.identifier.uri | https://doi.org/10.1016/j.jorganchem.2014.11.006 | - |
| dc.identifier.uri | https://dspace.iiti.ac.in/handle/123456789/9310 | - |
| dc.description.abstract | We report the synthesis of meso-tetrakis(ferrocenylethynylphenyl) porphyrins P1, P2 and the zinc derivative ZnP2. The photophysical and electrochemical properties of these porphyrins show substantial donor-acceptor interaction. The computational studies reveal that the para-linkage of the ferrocenyl unit in porphyrin P1 provides better π-conjugation compared to meta-linkage in porphyrin P2, which results in low HOMO-LUMO gap and red shifted absorption. The porphyrin P2 and ZnP2 show better thermal stability compared to the porphyrin P1. ©2014 Elsevier B.V. All rights reserved. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier | en_US |
| dc.source | Journal of Organometallic Chemistry | en_US |
| dc.subject | Organometallics | en_US |
| dc.subject | Computational studies | en_US |
| dc.subject | Donor-acceptor interaction | en_US |
| dc.subject | Donor-acceptors | en_US |
| dc.subject | Electrochemical | en_US |
| dc.subject | Ferrocenes | en_US |
| dc.subject | HOMO-LUMO gaps | en_US |
| dc.subject | Para-linkage | en_US |
| dc.subject | Photophysical | en_US |
| dc.subject | Porphyrins | en_US |
| dc.title | Meso-tetrakis(ferrocenylethynylphenyl) porphyrins: Synthesis and properties | en_US |
| dc.type | Journal Article | en_US |
| Appears in Collections: | Department of Chemistry | |
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