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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Misra, Rajneesh | en_US |
dc.date.accessioned | 2022-03-17T01:00:00Z | - |
dc.date.accessioned | 2022-03-21T11:32:18Z | - |
dc.date.available | 2022-03-17T01:00:00Z | - |
dc.date.available | 2022-03-21T11:32:18Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Gautam, P., Maragani, R., & Misra, R. (2015). Aryl-substituted symmetrical and unsymmetrical benzothiadiazoles. RSC Advances, 5(24), 18288-18294. doi:10.1039/c4ra15424j | en_US |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.other | EID(2-s2.0-84923249658) | - |
dc.identifier.uri | https://doi.org/10.1039/c4ra15424j | - |
dc.identifier.uri | https://dspace.iiti.ac.in/handle/123456789/9321 | - |
dc.description.abstract | A set of benzothiadiazoles (BTD) of the type D-π-A-π-D and D1-π-A-π-D2 were designed and synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction. Their photophysical and electrochemical properties were studied. The substitution of anthracene on BTD improves its thermal stability, and lowers the HOMO-LUMO gap, which results in a red shift of the electronic absorption. The experimental optical gap values show good agreement with the calculated HOMO-LUMO gap. © The Royal Society of Chemistry 2015. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.source | RSC Advances | en_US |
dc.subject | Benzothiadiazoles | en_US |
dc.subject | Electronic absorption | en_US |
dc.subject | HOMO-LUMO gaps | en_US |
dc.subject | Optical gap | en_US |
dc.subject | Photophysical | en_US |
dc.subject | Red shift | en_US |
dc.subject | Sonogashira cross-coupling reaction | en_US |
dc.subject | Chemical reactions | en_US |
dc.title | Aryl-substituted symmetrical and unsymmetrical benzothiadiazoles | en_US |
dc.type | Journal Article | en_US |
Appears in Collections: | Department of Chemistry |
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