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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/9326
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dc.contributor.authorMisra, Rajneeshen_US
dc.contributor.authorMobin, Shaikh M.en_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:32:20Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:32:20Z-
dc.date.issued2014-
dc.identifier.citationMisra, R., Maragani, R., Gautam, P., & Mobin, S. M. (2014). Tetracyanoethylene substituted triphenylamine analogues. Tetrahedron Letters, 55(51), 7102-7105. doi:10.1016/j.tetlet.2014.10.148en_US
dc.identifier.issn0040-4039-
dc.identifier.otherEID(2-s2.0-84911950138)-
dc.identifier.urihttps://doi.org/10.1016/j.tetlet.2014.10.148-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/9326-
dc.description.abstractA set of tetracyanoethylene (TCNE) substituted triphenylamine analogues (4-6) exhibiting strong intramolecular charge transfer (ICT) were designed and synthesized by the [2+2] cycloaddition-retroelectrocyclization reaction of 3 (tris-(4-phenylethynyl-phenyl)-amine) with TCNE. The reaction was found to be temperature dependent. The blue shift in the π → π∗ transition and intramolecular charge transfer (ICT) in amines 4-6 were found to be directly proportional to the number of TCNE units. The computational study shows good agreement with the experimental results and reveals that as the number of TCNE units in amine increases, HOMO-LUMO gap increases. © 2014 Elsevier Ltd. All rights reserved.en_US
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.sourceTetrahedron Lettersen_US
dc.subjectaniline derivativeen_US
dc.subjecttetracyanoethyleneen_US
dc.subjecttriphenylamine derivativeen_US
dc.subjecttris (4 phenylethynylphenyl)amineen_US
dc.subjectunclassified drugen_US
dc.subjectArticleen_US
dc.subjectchemical modificationen_US
dc.subjectcyclizationen_US
dc.subjectcycloadditionen_US
dc.subjectintramolecular charge transferen_US
dc.subjectretroelectrocyclizationen_US
dc.subjectsynthesisen_US
dc.subjecttemperatureen_US
dc.titleTetracyanoethylene substituted triphenylamine analoguesen_US
dc.typeJournal Articleen_US
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