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https://dspace.iiti.ac.in/handle/123456789/9330
| Title: | Thiophene/furan units decorated unsymmetrical dinuclear metallocalix[4]arenes |
| Authors: | Mobin, Shaikh M. |
| Keywords: | Benzimidazoles;Calix[4]arenes;Metallocavitand;Metallomacrocycles;Supramolecules;Rhenium |
| Issue Date: | 2014 |
| Publisher: | Elsevier |
| Citation: | Rajakannu, P., Mobin, S. M., & Sathiyendiran, M. (2014). Thiophene/furan units decorated unsymmetrical dinuclear metallocalix[4]arenes. Journal of Organometallic Chemistry, 771, 68-77. doi:10.1016/j.jorganchem.2014.03.028 |
| Abstract: | Twelve new dinuclear metallocalix[4]arenes (1-12) decorated with two thiophene units/two furan units were synthesized using a newly designed flexible ditopic nitrogen donors, a bis-chelating ligands, and Re2(CO)10 and were structurally characterized by various spectroscopic methods. The structures of 1, 5 and 9 were confirmed by single crystal X-ray diffraction analysis. The photophysical properties of the ligands were studied. The structures of 1, 3 and 5-12 were optimized using DFT-calculations. © 2014 Elsevier B.V. |
| URI: | https://doi.org/10.1016/j.jorganchem.2014.03.028 https://dspace.iiti.ac.in/handle/123456789/9330 |
| ISSN: | 0022-328X |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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