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Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/9397
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dc.contributor.authorMobin, Shaikh M.en_US
dc.date.accessioned2022-03-17T01:00:00Z-
dc.date.accessioned2022-03-21T11:32:47Z-
dc.date.available2022-03-17T01:00:00Z-
dc.date.available2022-03-21T11:32:47Z-
dc.date.issued2014-
dc.identifier.citationPatel, S. K., Tirkey, V., Mishra, S., Dash, H. R., Das, S., Shukla, M., . . . Chatterjee, S. (2014). Synthesis of mono- and bi-metallic dithiocarboxylate-alkyne complexes from sunlight driven insertion reaction and their antibacterial activity. Journal of Organometallic Chemistry, 749, 75-82. doi:10.1016/j.jorganchem.2013.09.018en_US
dc.identifier.issn0022-328X-
dc.identifier.otherEID(2-s2.0-84885355116)-
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2013.09.018-
dc.identifier.urihttps://dspace.iiti.ac.in/handle/123456789/9397-
dc.description.abstractSunlight driven synthesis, characterization and antibacterial evaluation of cyclopentadienyl based metal-dithiocarboxylate alkyne complexes, [LM(CO) n(η2-S2C)CCR], [{L = η5- C5H5, M = W, R = (η5-C5H 4)Fe(η5-C5H5), n = 2}; {L = η5-C5H5, M = W, R = -C(CH 3)CH2, n = 2}; {L = η5-C5H 5, M = Mo, R = -C(CH3)CH2, n = 2}; {L = η5-C5Me5, M = Fe, R = Ph, n = 1}] (5-8) have been carried out. Reactivity of metal-dithiocarboxylate alkyne complexes towards dicobaltoctacarbonyl were studied to obtain a trimetallic dithiocarboxylate complex (9-11). Structural characterizations of 7 and 8 have been carried out crystallographically and DFT calculation was performed on compound 8 to understand the electronic properties of the complex. © 2013 Elsevier B.V. All rights reserved.en_US
dc.language.isoenen_US
dc.sourceJournal of Organometallic Chemistryen_US
dc.subjectAnti-bacterial activityen_US
dc.subjectAntibacterialen_US
dc.subjectBio-organometallicen_US
dc.subjectCyclopentadienylsen_US
dc.subjectDithiocarboxylateen_US
dc.subjectInsertion reactionsen_US
dc.subjectStructural characterizationen_US
dc.subjectSunlighten_US
dc.subjectElectronic propertiesen_US
dc.subjectHydrocarbonsen_US
dc.subjectIron compoundsen_US
dc.subjectMolybdenumen_US
dc.subjectMolybdenum compoundsen_US
dc.subjectOrganometallicsen_US
dc.subjectSynthesis (chemical)en_US
dc.subjectTungstenen_US
dc.subjectTungsten compoundsen_US
dc.titleSynthesis of mono- and bi-metallic dithiocarboxylate-alkyne complexes from sunlight driven insertion reaction and their antibacterial activityen_US
dc.typeJournal Articleen_US
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