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| Title: | Formation of (E)-[FcC(PS2(OR)2)CH(PS 2(OR)2)] (R = Me, Et, iPr) in photolytic reactions of ferrocenylacetylene and [(RO)2PS2H] in hexane/alcohols: Experimental and DFT study |
| Authors: | Mathur, Pradeep Radhe Shyam Pathak, Biswarup Mobin, Shaikh M. |
| Keywords: | DFT;DFT study;Dialkyldithiophosphate;Different solvents;Ethene;Ferrocenylacetylene;Low temperatures;Photolytic reactions;Crystal structure;Photochemical reactions;Ethylene |
| Issue Date: | 2013 |
| Citation: | Mathur, P., Ji, R. S., Pathak, B., & Mobin, S. M. (2013). Formation of (E)-[FcC(PS2(OR)2)CH(PS 2(OR)2)] (R = me, et, iPr) in photolytic reactions of ferrocenylacetylene and [(RO)2PS2H] in hexane/alcohols: Experimental and DFT study. Journal of Organometallic Chemistry, 748, 46-50. doi:10.1016/j.jorganchem.2013.04.021 |
| Abstract: | Photochemical reactions of ferrocenylacetylene with dialkyldithiophosphoric acid in hexane at low temperature led to the formation of (E)-[FcC(PS 2(OR)2)CH(PS2(OR)2)] (R = Me, Et, iPr). Formation of these compounds have been studied experimentally and computationally in different solvents. © 2013 Elsevier B.V. All rights reserved. |
| URI: | https://doi.org/10.1016/j.jorganchem.2013.04.021 https://dspace.iiti.ac.in/handle/123456789/9431 |
| ISSN: | 0022-328X |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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