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https://dspace.iiti.ac.in/handle/123456789/9434
Title: | Rauhut-currier reaction of nitroalkenes with vinyl sulfones |
Authors: | Mobin, Shaikh M. |
Keywords: | Catalyst system;Ketoximes;Nitroalkenes;One pot;Vinyl sulfones;Chemistry;Organic compounds;1 bis sulfonyl 3 nitroalkene;alkene derivative;dioxane;imidazole;sulfone derivative;unclassified drug;article;catalyst;chemical reaction;chemical structure;dielectric constant;electron transport;rauhut currier reaction;stoichiometry;tautomerization;Alkenes;Molecular Structure;Nitro Compounds;Oximes;Sulfones |
Issue Date: | 2013 |
Citation: | Kumar, R., Kumar, T., Mobin, S. M., & Nambothiri, I. N. N. (2013). Rauhut-currier reaction of nitroalkenes with vinyl sulfones. Journal of Organic Chemistry, 78(10), 5073-5077. doi:10.1021/jo400528j |
Abstract: | The Rauhut-Currier reaction between nitroalkenes and vinyl sulfones has been successfully carried out for the first time. The reaction proceeds in the presence of an imidazole/LiCl catalyst system in dioxane to provide the adducts possessing a synthetically useful 1-bis-sulfonyl-3-nitroalkene moiety in good to excellent yield. A one-pot transformation of the products to β-sulfonyl-α,β-unsaturated ketoximes has also been demonstrated. © 2013 American Chemical Society. |
URI: | https://doi.org/10.1021/jo400528j https://dspace.iiti.ac.in/handle/123456789/9434 |
ISSN: | 0022-3263 |
Type of Material: | Journal Article |
Appears in Collections: | Department of Chemistry |
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