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| Title: | Synthesis, structure and redox property of first 1,2,3-triselenole |
| Authors: | Mathur, Pradeep Rai, Dhirendra Kumar Mobin, Shaikh M. |
| Keywords: | Chalcogenole;Demetallation;Redox property;Triselenole;Cyclic voltammetry;Hexane;Photolysis;Synthesis (chemical) |
| Issue Date: | 2012 |
| Citation: | Mathur, P., Rai, D. K., Tauqeer, M., Joshi, R. K., Lahiri, G. K., & Mobin, S. M. (2012). Synthesis, structure and redox property of first 1,2,3-triselenole. Journal of Organometallic Chemistry, 721-722, 144-147. doi:10.1016/j.jorganchem.2012.09.009 |
| Abstract: | Photolysis of [Fe3Se2(CO)9] with 3-ferrocenylpropynal in hexane yields an adduct of [Fe2Se 2(CO)6] and FcC2CHO, [(CO)6Fe 2{μ-SeC(Fc)C(CHO)Se}] (1). Subsequent reaction of 1 with [Fe 2Se2(CO)6] in presence of excess of Me 3NO·2H2O in THF leads to formation of a novel 5-ferrocenyl-4-carbaldehyde-1,2,3-triselenole (2). Its electrochemistry has been investigated by cyclic voltammetry, which shows two successive quasi-reversible oxidations. © 2012 Elsevier B.V. All rights reserved. |
| URI: | https://doi.org/10.1016/j.jorganchem.2012.09.009 https://dspace.iiti.ac.in/handle/123456789/9458 |
| ISSN: | 0022-328X |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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