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| Title: | Synthesis and characterization of a novel unfused 1, 4-diselenine |
| Authors: | Mathur, Pradeep Radhe Shyam Mobin, Shaikh M. |
| Keywords: | Irradiation;Microwave irradiation;Nuclear magnetic resonance spectroscopy;Single crystals;X ray diffraction;1,4-Diselenine;13C NMR spectroscopy;Chalcogens;Clusters;Ethynylferrocene;Single crystal X-ray diffraction method;Synthesis and characterizations;Toluene solution;Crystal structure |
| Issue Date: | 2012 |
| Publisher: | Elsevier B.V. |
| Citation: | Mathur, P., Ji, R. S., Tauqeer, M., Lahiri, G. K., & Mobin, S. M. (2012). Synthesis and characterization of a novel unfused 1, 4-diselenine. Journal of Organometallic Chemistry, 721-722, 186-189. doi:10.1016/j.jorganchem.2012.09.006 |
| Abstract: | Microwave irradiation of toluene solution of mixed-chalcogen clusters [Fe3(CO)9(μ3-E)(μ3-E′)] (E, E′ = S, Se or Te, and E ≠ E′) with ethynylferrocene and TMNO·2H2O afforded 2,5-diferrocenyldiselenine (1), 2,5-diferrocenylselenophene (2), 2,6-diferrocenylthiine (4) and 2,5-diferrocenylthiophene (5), and the adducts Fe2(CO) 6{(μ-E)2C(Fc) = CH} [E = Se(3), S(6)]. 1-6 have been characterized by IR, and 1H NMR and 13C NMR spectroscopy. Structure 1 was established by single crystal X-ray diffraction method. © 2012 Elsevier B.V. All rights reserved. |
| URI: | https://doi.org/10.1016/j.jorganchem.2012.09.006 https://dspace.iiti.ac.in/handle/123456789/9459 |
| ISSN: | 0022-328X |
| Type of Material: | Short Survey |
| Appears in Collections: | Department of Chemistry |
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