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| Title: | Synthesis and molecular structure of [((CO)3RuBr 2)2(μ-SePh)2Ru(CO)4] cluster with a Ru3Se2 chain core |
| Authors: | Mathur, Pradeep |
| Keywords: | Chain-like;Cluster;Cluster cores;Monomeric complexes;Ruthenium carbonyl;Single crystal XRD;Tellurenyl;Crystal structure;Diffraction;Molecular structure;Phase change memory;Ruthenium;Selenium;Single crystals;Synthesis (chemical);X ray diffraction;Ruthenium compounds |
| Issue Date: | 2011 |
| Citation: | Torubaev, Y., Mathur, P., & Pasynskii, A. (2011). Synthesis and molecular structure of [((CO)3RuBr 2)2(μ-SePh)2Ru(CO)4] cluster with a Ru3Se2 chain core. Journal of Organometallic Chemistry, 696(4), 832-834. doi:10.1016/j.jorganchem.2010.10.036 |
| Abstract: | Treatment of ruthenium carbonyl, [Ru3(CO)12] with phenylseleno tribromide PhSeBr3 afforded a new triruthenium cluster, [(CO)10Br4Ru3(μ-SePh)2] (1). Its molecular structure was determined by single crystal XRD method (P2 1/c; a = 10.514(3) Å ; b = 10.814(3) Å ; c = 19.063(5)Å ; β = 105.064(4)°; V = 2093.1(10)Å 3) and shown to have two lateral Ru(CO)3Br2 units attached via two PhSe bridges to a Ru(CO)4 center forming a chain-like Ru-Se-Ru-Se-Ru cluster core. This is in contrast with a recently reported reaction of PhTeBr3 with [Ru3(CO)12] which formed a monomeric complex of ruthenium-dicarbonyl-dibromo fragment coordinating two PhTeBr ligands, [(CO)2RuBr2(PhTeBr)2]. © 2010 Elsevier B.V. All rights reserved. |
| URI: | https://doi.org/10.1016/j.jorganchem.2010.10.036 https://dspace.iiti.ac.in/handle/123456789/9481 |
| ISSN: | 0022-328X |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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