Please use this identifier to cite or link to this item: https://dspace.iiti.ac.in/handle/123456789/16431
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dc.contributor.authorKushwaha, Ajay Kumaren_US
dc.contributor.authorKumar, Ravinderen_US
dc.contributor.authorSonwane, Akshay Kumaren_US
dc.contributor.authorSamal, Sonalien_US
dc.date.accessioned2025-07-09T13:48:02Z-
dc.date.available2025-07-09T13:48:02Z-
dc.date.issued2025-
dc.identifier.citationShcherbakova-Sandu, M. P., Gulevich, S. A., Meshcheryakov, E. P., Kazantseva, K. I., Chernyavskii, A. V., Pestryakov, A. N., Kushwaha, A. K., Kumar, R., Sonwane, A. K., Samal, S., Samal, S., & Kurzina, I. A. (2025). Exploring the Impact of Bi Content in Nanostructured Pd-Bi Catalysts Used for Selective Oxidation of Glucose: Synthesis, Characterization and Catalytic Properties. Inorganics, 13(6). https://doi.org/10.3390/inorganics13060205en_US
dc.identifier.issn2304-6740-
dc.identifier.otherEID(2-s2.0-105008928306)-
dc.identifier.urihttps://dx.doi.org/10.3390/inorganics13060205-
dc.identifier.urihttps://dspace.iiti.ac.in:8080/jspui/handle/123456789/16431-
dc.description.abstractThis work is devoted to the study of the effect of small Bi additives on the functional properties of Pdx:Bi/Al2O3 catalysts in the selective oxidation of glucose to gluconic acid. The catalysts obtained by the joint impregnation method were characterized (TEM) by high dispersion of bimetallic nanoparticles with a median diameter of 4–5 nm. The structure of the Pd-Bi solid solution was confirmed via XPS and showed a change in the valence state of Pd and Bi depending on the Bi content, as well as the fraction of the oxidized state of Bi. TPR-H2 revealed various forms of Pd, including PdO and mixed Pd-O-Bi structures. The Pd10:Bi1/Al2O3 catalyst demonstrated the highest efficiency (77.2% glucose conversion, 96% sodium gluconate selectivity), which is due to the optimal ratio between Pd and Bi, ensuring the stabilization of metallic Pd and preventing its oxidation. © 2025 by the authors.en_US
dc.language.isoenen_US
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)en_US
dc.sourceInorganicsen_US
dc.subjectbimetallic nanoparticlesen_US
dc.subjectheterogeneous catalysisen_US
dc.subjectinfluence of Bien_US
dc.subjectinfluence of modifieren_US
dc.subjectPd-Bi catalystsen_US
dc.subjectselective oxidation of glucoseen_US
dc.subjectsodium gluconateen_US
dc.titleExploring the Impact of Bi Content in Nanostructured Pd-Bi Catalysts Used for Selective Oxidation of Glucose: Synthesis, Characterization and Catalytic Propertiesen_US
dc.typeJournal Articleen_US
Appears in Collections:Department of Chemistry
Department of Mechanical Engineering

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