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| Title: | Redox-Active Peptide-Functionalized Quinquethiophene-Based Electrochromic π-Gel |
| Authors: | Konda, Maruthi Maiti, Sayan Jadhav, Rohit G. Das, Apurba Kumar |
| Keywords: | Electrochromism;Gels;Peptides;Redox reactions;Scaffolds;Assembly systems;Bolaamphiphiles;Controlled switching;Electrochromic properties;Electrochromics;Functionalized;Molecular self assembly;Relative orientation;Self assembly;peptide;thiophene derivative;chemical structure;chemistry;electrochemical analysis;gel;oxidation reduction reaction;synthesis;Electrochemical Techniques;Gels;Molecular Structure;Oxidation-Reduction;Peptides;Thiophenes |
| Issue Date: | 2018 |
| Publisher: | John Wiley and Sons Ltd |
| Citation: | Konda, M., Maiti, S., Jadhav, R. G., & Das, A. K. (2018). Redox-active peptide-functionalized quinquethiophene-based electrochromic π-gel. Chemistry - an Asian Journal, 13(2), 204-209. doi:10.1002/asia.201701460 |
| Abstract: | An electrochromic system based on a self-assembled dipeptide-appended redox-active quinquethiophene π-gel is reported. The designed peptide-quinquethiophene consists of a symmetric bolaamphiphile that has two segments: a redox-active π-conjugated quinquethiophene core for electrochromism, and peptide motif for the involvement of molecular self-assembly. Investigations reveal that self-assembly and electrochromic properties of the π-gel are strongly dependent on the relative orientation of peptidic and quinquethiophene scaffolds in the self-assembly system. The colors of the π-gel film are very stable with fast and controlled switching speed at room temperature. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
| URI: | https://doi.org/10.1002/asia.201701460 https://dspace.iiti.ac.in/handle/123456789/9056 |
| ISSN: | 1861-4728 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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