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https://dspace.iiti.ac.in/handle/123456789/9147
Title: | A new multitalented azine ligand: Elastic bending, single-crystal-to-single-crystal transformation and a fluorescence turn-on Al(III) sensor |
Authors: | Natarajan, Kaushik Mobin, Shaikh M. |
Keywords: | aluminum;azine ligand;azobenzene;crystallin;ligand;unclassified drug;Article;chemical structure;complex formation;crystal structure;electrospray mass spectrometry;fluorescence;limit of detection;phase transition;sensor;single crystal to single crystal transformation;solid state;synthesis |
Issue Date: | 2017 |
Publisher: | Royal Society of Chemistry |
Citation: | Saini, A. K., Natarajan, K., & Mobin, S. M. (2017). A new multitalented azine ligand: Elastic bending, single-crystal-to-single-crystal transformation and a fluorescence turn-on al(III) sensor. Chemical Communications, 53(71), 9870-9873. doi:10.1039/c7cc04392a |
Abstract: | We report a rare combination of two unique properties of an azine based ligand (H3L): in a solid-state crystalline material it shows highly flexible and elastic behavior which on triggering with light results in slight deviation with phase transformation at the Single-Crystal-to-Single-Crystal (SCSC) level. Furthermore, in the solution state it acts as a highly selective, sensitive and reversible Al3+ sensor with a detection limit of 42 nM. © 2017 The Royal Society of Chemistry. |
URI: | https://doi.org/10.1039/c7cc04392a https://dspace.iiti.ac.in/handle/123456789/9147 |
ISSN: | 1359-7345 |
Type of Material: | Journal Article |
Appears in Collections: | Department of Chemistry |
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