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https://dspace.iiti.ac.in/handle/123456789/9241
| Title: | Molecular complexity and diversity from aromatics. Intramolecular cycloaddition of cyclohexa-2,4-dienones and sigmatropic shift in excited state: a unified approach towards synthesis of polycyclic frameworks related to crotogoudin, conidiogenol, and crinipellins |
| Authors: | Mobin, Shaikh M. |
| Keywords: | aromatic compound;conidiogenol;crinipellin;crotogoudin;cyclohexa 2,4 dienone derivative;diterpenoid;unclassified drug;aromatization;Article;cycloaddition;Diels Alder reaction;oxidation;photoreactivity;priority journal;reaction analysis;synthesis |
| Issue Date: | 2016 |
| Publisher: | Elsevier Ltd |
| Citation: | Behera, T. K., Jarhad, D. B., Mobin, S. M., & Singh, V. (2016). Molecular complexity and diversity from aromatics. intramolecular cycloaddition of cyclohexa-2,4-dienones and sigmatropic shift in excited state: A unified approach towards synthesis of polycyclic frameworks related to crotogoudin, conidiogenol, and crinipellins. Tetrahedron, 72(35), 5377-5393. doi:10.1016/j.tet.2016.07.023 |
| Abstract: | Synthesis of polycyclic systems related to conidiogenol, crinipellin, and crotogoudin from simple aromatic precursor has been described. Oxidative dearomatization, tandem retro-Diels–Alder/Diels–Alder reaction, and photoreaction are the key features of our approach. © 2016 Elsevier Ltd |
| URI: | https://doi.org/10.1016/j.tet.2016.07.023 https://dspace.iiti.ac.in/handle/123456789/9241 |
| ISSN: | 0040-4020 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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