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| Title: | Oxidation of ferrocene and 1,1'-ferrocene triselenide by bromine and phenyltellurium tribromide |
| Authors: | Raghuvanshi, Abhinav Mobin, Shaikh M. |
| Keywords: | Bromine;Iron compounds;Organometallics;X ray diffraction analysis;Compound I;Crystallization conditions;Ferrocenes;Bromine compounds |
| Issue Date: | 2015 |
| Publisher: | Maik Nauka Publishing / Springer SBM |
| Citation: | Torubaev, Y. V., Pavlova, A. V., Pasynskii, A. A., Raghuvanshi, A., & Shaikh, M. M. (2015). Oxidation of ferrocene and 1,1'-ferrocene triselenide by bromine and phenyltellurium tribromide. Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 41(10), 638-643. doi:10.1134/S1070328415100085 |
| Abstract: | The reaction of 1,1'-ferrocene triselenide, Fe(C5H4)2Se3 (I), with bromine or phenyltellurium tribromide, PhTeBr3, involves the oxidation of compound I to form salts [Fe(C5H4)2Se3]+FeBr 4 - (II) and [Fe(C5H4)2Se3]+PhTeBr 4 - (III), respectively. Depending on the crystallization conditions, the reaction of ferrocene with PhTeBr3 affords salt [Fc]+[PhTeBr4]- (IVa), its solvate with benzene{[Fc]+[PhTeBr4]-}2 · C6H6 (IVb), or etherate [Fc]+[Ph2Te2Br6OH]- · 0.5(C2H5)2O (V). The structures of compounds II, III, IVa, IVb, and V are determined by X-ray diffraction analysis (CIF files CCDC 1054193 (II), 1054192 (III), 1054194 (IVa), 1054195 (IVb), and 1054196 (V)). © 2015 Pleiades Publishing, Ltd. |
| URI: | https://doi.org/10.1134/S1070328415100085 https://dspace.iiti.ac.in/handle/123456789/9269 |
| ISSN: | 1070-3284 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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