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| Title: | Ferrocenyl-cymantrenyl hetero-bimetallic chalcones: Synthesis, structure and biological properties |
| Authors: | Mobin, Shaikh M. |
| Keywords: | Manganese;Organometallics;Phosphorus compounds;Single crystals;Anti-bacterial activity;Bis(diphenylphosphino) ferrocene;Chalcones;Cyclic voltammetric techniques;Cymantrenyl;Ferrocenyl;Phosphine;Structural characterization;Iron compounds;Bacteria (microorganisms);Plasmodium falciparum |
| Issue Date: | 2015 |
| Publisher: | Elsevier |
| Citation: | Mishra, S., Tirkey, V., Ghosh, A., Dash, H. R., Das, S., Shukla, M., . . . Chatterjee, S. (2015). Ferrocenyl-cymantrenyl hetero-bimetallic chalcones: Synthesis, structure and biological properties. Journal of Molecular Structure, 1085, 162-172. doi:10.1016/j.molstruc.2014.12.070 |
| Abstract: | Two new ferrocenyl-cymantrenyl bimetallic chalcones, [(CO)3Mn(η5-C5H4)C(O)CHCH(η5-C5H4)Fe(η5-C5H5)] (1) and [{(CO)3Mn(η5-C5H4)C(O)CHCH(η5-C5H4)}2Fe] (2) have been synthesized. Their reactivity study with triphenylphosphine and bis-(diphenylphosphino)ferrocene led to the isolation of phosphine substituted bimetallic chalcones (3-6). Single crystal X-ray structural characterization for 1 and its phosphine analogue (3) reveals their different conformational identity with anti-conformation for 1, while syn-conformation for 3. Investigation of antimalarial and antibacterial activities was carried out for compounds 1 and 2 against two strains of Plasmodium falciparum (3D7, K1) and four bacterial strains. TD-DFT calculation was performed for compound 1 and electrochemical properties were studied for bimetallic chalcone compounds by cyclic voltammetric technique. © 2015 Elsevier B.V. All rights reserved. |
| URI: | https://doi.org/10.1016/j.molstruc.2014.12.070 https://dspace.iiti.ac.in/handle/123456789/9298 |
| ISSN: | 0022-2860 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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