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| Title: | Molecular diversity from aromatics. Cycloaddition of cyclohexa-2,4-dienones, ring-closing metathesis and sigmatropic shifts: A general and stereoselective route to novel spirocarbocyclics |
| Authors: | Mobin, Shaikh M. |
| Keywords: | 2 hydroxymethylphenol derivative;aromatic compound;bicyclo[2.2.2]octane derivative;bicyclo[2.2.2]octenone derivative;bicyclo[3.3.0]octane derivative;bicyclo[4.2.0]octane derivative;epoxide;phenol derivative;spiroepoxycyclohexadienone derivative;unclassified drug;aromatization;Article;cycloaddition;oxidation;oxidative dearomatization;photochemistry;ring closing metathesis;stereochemistry;Alnus |
| Issue Date: | 2015 |
| Publisher: | Elsevier Ltd |
| Citation: | Singh, V., Das, B., Jarhad, D. B., & Mobin, S. M. (2015). Molecular diversity from aromatics. cycloaddition of cyclohexa-2,4-dienones, ring-closing metathesis and sigmatropic shifts: A general and stereoselective route to novel spirocarbocyclics. Tetrahedron, 71(4), 560-576. doi:10.1016/j.tet.2014.12.033 |
| Abstract: | A novel, general and stereoselective route to spiroannulated bicyclo[2.2.2]octenones and their transformation to spiroannulated bicyclo[3.3.0]- and bicyclo[4.2.0]octanes is described. Oxidative dearomatization of o-hydroxymethylphenols, cycloaddition of spiroepoxycyclohexadienones, ring-closing metathesis and photochemical sigmatropic 1,2- and 1,3-acyl shifts are the key features of our methodology. ©2014 Elsevier Ltd. All rights reserved. |
| URI: | https://doi.org/10.1016/j.tet.2014.12.033 https://dspace.iiti.ac.in/handle/123456789/9308 |
| ISSN: | 0040-4020 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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