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| Title: | Studies on synthesis of spirolactone annulated bicyclo[2.2.2]octanes: Tricyclic core of yaoshanenolides |
| Authors: | Mobin, Shaikh M. |
| Keywords: | bicyclo[2.2.2]octane derivative;spironolactone;alkylation;article;carbon nuclear magnetic resonance;column chromatography;crystal structure;cycloaddition;decarboxylation;Diels Alder reaction;Grignard reaction;Jones oxidation;nucleophilicity;priority journal;proton nuclear magnetic resonance;ring closing metathesis;stereochemistry;stereoisomerism;synthesis;thin layer chromatography;X ray analysis |
| Issue Date: | 2014 |
| Publisher: | Elsevier Ltd |
| Citation: | Das, B., Mobin, S. M., & Singh, V. (2014). Studies on synthesis of spirolactone annulated bicyclo[2.2.2]octanes: Tricyclic core of yaoshanenolides. Tetrahedron, 70(32), 4768-4777. doi:10.1016/j.tet.2014.05.043 |
| Abstract: | A stereoselective approach to tricyclic core of yaoshanenolides from simple aromatic precursor is described. Cycloaddition of highly reactive spiroepoxycyclohexa-2,4-dienone, stereoselective Grignard reaction, alkylation, and ring-closing metathesis reaction are the key features of our approach. © 2014 Elsevier Ltd. All rights reserved. |
| URI: | https://doi.org/10.1016/j.tet.2014.05.043 https://dspace.iiti.ac.in/handle/123456789/9343 |
| ISSN: | 0040-4020 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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