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| Title: | Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl |
| Authors: | Mathur, Pradeep Raghuvanshi, Abhinav Radhe Shyam Mobin, Shaikh M. |
| Keywords: | Acetylides;Adduct;Iron pentacarbonyls;Mixed metal clusters;Reaction conditions;Ruthenium acetylide;Thermal condition;Photolysis;Ruthenium |
| Issue Date: | 2013 |
| Citation: | Mathur, P., Raghuvanshi, A., Ji, R. S., & Mobin, S. M. (2013). Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl. Journal of Organometallic Chemistry, 731, 55-60. doi:10.1016/j.jorganchem.2013.02.001 |
| Abstract: | Photolysis of a THF solution containing ruthenium acetylide [(η5-C5H5)Ru(PPh3) 2(η1-CCPh)] with [Fe3(CO) 9(μ3-Se)2] cluster affords an adduct [{μ-SeC(CpRu(PPh3)(CO))C(Ph)Se}(CO)6Fe2] (1), while under similar reaction condition with [Fe3(CO) 9(μ3-Te)2] cluster a Ru-inserted product [(η5-C5H5)(PPh3) (η1-CCPh)RuFe2(μ3-Te) 2(CO)6] (2) was obtained. Under thermal condition [(η5-C5H5)Ru(PPh3) 2(η1-CCPh)] react with Fe(CO)5 to give an acetylide stabilised Fe2Ru mixed metal cluster [(η5- C5H5)RuFe2(CO)7(η2: η2:η1-CCPh)], (3). © 2013 Elsevier B.V. All rights reserved. |
| URI: | https://doi.org/10.1016/j.jorganchem.2013.02.001 https://dspace.iiti.ac.in/handle/123456789/9440 |
| ISSN: | 0022-328X |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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