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https://dspace.iiti.ac.in/handle/123456789/9043
| Title: | Vacuum-Mediated Single-Crystal-to-Single-Crystal (SCSC) Transformation in Na-MOFs: Rare to Novel Topology and Activation of Nitrogen in Triazole Moieties |
| Authors: | Ansari, Shagufi Naz Mobin, Shaikh M. |
| Keywords: | Chemical activation;Chromium compounds;Crystal lattices;Sodium;Sodium compounds;Topology;X ray diffraction;In-situ synthesis;Net topology;Powder X ray diffraction;X-ray studies;Single crystals |
| Issue Date: | 2018 |
| Publisher: | American Chemical Society |
| Citation: | Ansari, S. N., Verma, S. K., Garin, A. A., & Mobin, S. M. (2018). Vacuum-mediated single-crystal-to-single-crystal (SCSC) transformation in na-MOFs: Rare to novel topology and activation of nitrogen in triazole moieties. Crystal Growth and Design, 18(3), 1287-1292. doi:10.1021/acs.cgd.7b01753 |
| Abstract: | We report a rare example of facile in situ synthesis of Na-MOF1 that undergoes vacuum-mediated single-crystal-to-single-crystal (SCSC) transformations from rare parallel polycatenated kgd nets to new and novel 3-periodic 3,3,12-c net topology (named smm1). Further, SCSC transformation of Na-MOF1 to Na-MOF2 reveals activation of N-N atoms in 1,2,3-triazole unit. Na-MOF1 and Na-MOF2 were authenticated by single-crystal X-ray studies, and the bulk was confirmed by powder X-ray diffraction studies. © 2018 American Chemical Society. |
| URI: | https://doi.org/10.1021/acs.cgd.7b01753 https://dspace.iiti.ac.in/handle/123456789/9043 |
| ISSN: | 1528-7483 |
| Type of Material: | Journal Article |
| Appears in Collections: | Department of Chemistry |
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